WEKO3
アイテム
Ti–Pd Alloys as Heterogeneous Catalysts for Hydrogen Autotransfer Reaction and Catalytic Improvement by Hydrogenation Effects
http://hdl.handle.net/10112/00017634
http://hdl.handle.net/10112/0001763402404ccf-737b-4193-81bb-81c2ac1d483b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-0020-20190328-01.pdf (691.1 kB)
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| Item type | 研究報告書 / Research Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2020-03-28 | |||||
| タイトル | ||||||
| タイトル | Ti–Pd Alloys as Heterogeneous Catalysts for Hydrogen Autotransfer Reaction and Catalytic Improvement by Hydrogenation Effects | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
| 資源タイプ | research report | |||||
| 著者 |
Takahashi, Yuya
× Takahashi, Yuya× 近藤, 亮太× Utsunomiya, Masayoshi× Suzuki, Takeyuki× 竹下, 博之× Obora, Yasushi |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 34783 | |||||
| 姓名 | 近藤, 亮太 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 34784 | |||||
| 姓名 | 竹下, 博之 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 34785 | |||||
| 姓名 | 大洞, 康嗣 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Ti−Pd alloys were investigated as heterogeneous catalysts for hydrogen autotransfer reactions. This is the first reported study of alloys as catalysts for hydrogen‐borrowing reactions using alcohols. We improved the catalytic activities of alloys by increasing their specific surface areas via a hydrogenation−powdering process. The reactivities and selectivities of hydrogenated Ti−Pd alloys [Ti−Pd (Hy) ] were higher than those of non‐hydrogenated alloy catalysts in N‐alkylation by hydrogen autotransfer using alcohols. A plausible catalytic cycle is proposed based on control studies and deuterium labelling experiments. | |||||
| 書誌情報 |
ChemCatChem 巻 11, 号 10, 発行日 2019-03-28 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 18673880 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12433532 | |||||
| 権利 | ||||||
| 権利情報 | This is the peer reviewed version of the following article: Ti−Pd Alloys as Heterogeneous Catalysts for the Hydrogen Autotransfer Reaction and Catalytic Improvement by Hydrogenation Effects, Y. Takahashi, R. Kondo, M. Utsunomiya, T. Suzuki, H. T. Takeshita, Y. Obora, ChemCatChem 2019, 11, 2432., which has been published in final form at https://doi.org/10.1002/cctc.201900318. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | 関西大学 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Kansai University | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Alloy catalysts | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Hydrogen transfer | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Alkylation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Alcohols | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Heterogeneous catalysis | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
