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Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands
http://hdl.handle.net/10112/5938
http://hdl.handle.net/10112/59389217a706-d52e-4e4d-874e-8094ef5bf857
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-20000106-03.pdf (292.7 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2012-01-26 | |||||
| タイトル | ||||||
| タイトル | Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Yamanari, Kazuaki
× Yamanari, Kazuaki× Fukuda, Ito× Yamamoto, Shiori× Kushi, Yoshihiko× Fuyuhiro, Akira× Kubota, Naoko× Fukuo, Tsuyoshi× Arakawa, Ryuichi |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26894 | |||||
| 姓名 | 山成, 数明 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26895 | |||||
| 姓名 | 福田, 伊都 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26896 | |||||
| 姓名 | 山本, しをり | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26897 | |||||
| 姓名 | 久司, 佳彦 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26898 | |||||
| 姓名 | 冬広, 明 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26899 | |||||
| 姓名 | 久保田, 直子 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26900 | |||||
| 姓名 | 福尾, 剛志 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26901 | |||||
| 姓名 | 荒川, 隆一 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Self-assembling reactions between [Rh(η5-C5Me5)(H2O)3]2+and pyrimidine-2-thionate(pymt) or related ligands [L; mpymt = 4-methyl-pyrimidine-2-thionate(1-), dmpymt = 4,6-dimethylpyrimidine-2-thionate(1-), apymt = 4-aminopyrimidine-2-thionate(1-), dapymt = 4,6-diaminopyrimidine-2-thionate(1-), or mpol = 2-sulfanyl-3-pyridinolate(2-)] were carried out and the products characterized by UV/vis, NMR spectroscopy, electrospray ionization mass spectrometry, and crystal structure analysis. All products are dinuclear rhodium(III) complexes of [{Rh(η5-C5Me5)(L)}2]n+: three crystal structures with mpymt, dmpymt and mpol were determined. The mpymt and dmpymt ligands co-ordinate through a 1κ2N,S:2κS mode and the two pyrimidine rings are located in cis position,whereas mpol adopts a five-membered chelating mode with 1κ2S,O:2κS and the two pyrimidine rings are located in trans position. Such structural difference can reasonably be explained by the intramolecular stacking interaction between the two bridging ligands. |
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| 書誌情報 |
Journal of the Chemical Society, Dalton Transactions 巻 2000, 号 13, p. 2131-2136, 発行日 2000-01-06 |
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| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1039/B000098L | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | Royal Society of Chemistry | |||||
