{"created":"2023-05-15T12:20:49.203177+00:00","id":11520,"links":{},"metadata":{"_buckets":{"deposit":"5c4f49bf-dd5d-4cd7-ac3d-f1dd830dc26d"},"_deposit":{"created_by":1,"id":"11520","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11520"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011520","sets":["528:1588:1595:1597"]},"author_link":["26887","26889","26888","26892","26899","26900","26901","26895","26894","26890","26898","26893","26891","26897","26896","26886"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000-01-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"13","bibliographicPageEnd":"2136","bibliographicPageStart":"2131","bibliographicVolumeNumber":"2000","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society, Dalton Transactions"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Self-assembling reactions between [Rh(η5-C5Me5)(H2O)3]2+and pyrimidine-2-thionate(pymt) or related ligands\n[L; mpymt = 4-methyl-pyrimidine-2-thionate(1-), dmpymt = 4,6-dimethylpyrimidine-2-thionate(1-), apymt = 4-aminopyrimidine-2-thionate(1-), dapymt = 4,6-diaminopyrimidine-2-thionate(1-), or mpol = 2-sulfanyl-3-pyridinolate(2-)] were carried out and the products characterized by UV/vis, NMR spectroscopy, electrospray \nionization mass spectrometry, and crystal structure analysis. All products are dinuclear rhodium(III) complexes of \n[{Rh(η5-C5Me5)(L)}2]n+: three crystal structures with mpymt, dmpymt and mpol were determined. The mpymt and dmpymt ligands co-ordinate through a 1κ2N,S:2κS mode and the two pyrimidine rings are located in cis position,whereas mpol adopts a five-membered chelating mode with 1κ2S,O:2κS and the two pyrimidine rings are located in trans position. Such structural difference can reasonably be explained by the　intramolecular stacking interaction between the two bridging ligands.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"26894","nameIdentifierScheme":"WEKO"}],"names":[{"name":"山成, 数明"}]},{"nameIdentifiers":[{"nameIdentifier":"26895","nameIdentifierScheme":"WEKO"}],"names":[{"name":"福田, 伊都"}]},{"nameIdentifiers":[{"nameIdentifier":"26896","nameIdentifierScheme":"WEKO"}],"names":[{"name":"山本, しをり"}]},{"nameIdentifiers":[{"nameIdentifier":"26897","nameIdentifierScheme":"WEKO"}],"names":[{"name":"久司, 佳彦"}]},{"nameIdentifiers":[{"nameIdentifier":"26898","nameIdentifierScheme":"WEKO"}],"names":[{"name":"冬広, 明"}]},{"nameIdentifiers":[{"nameIdentifier":"26899","nameIdentifierScheme":"WEKO"}],"names":[{"name":"久保田, 直子"}]},{"nameIdentifiers":[{"nameIdentifier":"26900","nameIdentifierScheme":"WEKO"}],"names":[{"name":"福尾, 剛志"}]},{"nameIdentifiers":[{"nameIdentifier":"26901","nameIdentifierScheme":"WEKO"}],"names":[{"name":"荒川, 隆一"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/B000098L","subitem_relation_type_select":"DOI"}}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamanari, Kazuaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukuda, Ito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamamoto, Shiori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kushi, Yoshihiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fuyuhiro, Akira"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kubota, Naoko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukuo, Tsuyoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arakawa, Ryuichi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20000106-03.pdf","filesize":[{"value":"292.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20000106-03.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11520/files/KU-1100-20000106-03.pdf"},"version_id":"b75e6b35-1a0a-4b53-9164-b09c255424db"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-01-26"},"publish_date":"2012-01-26","publish_status":"0","recid":"11520","relation_version_is_last":true,"title":["Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T19:15:30.884896+00:00"}