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Analysis of Electrolysis Reactions of Metal Complexes Using On-Line Electrospray Ionization Mass Spectrometry with a Compact Electrolytic Flow-Through Cell
http://hdl.handle.net/10112/5934
http://hdl.handle.net/10112/59341518412e-6799-4444-9e04-ecec0b772e6d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-19990215-13.pdf (726.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2012-01-26 | |||||
| タイトル | ||||||
| タイトル | Analysis of Electrolysis Reactions of Metal Complexes Using On-Line Electrospray Ionization Mass Spectrometry with a Compact Electrolytic Flow-Through Cell | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Arakawa, Ryuichi
× Arakawa, Ryuichi× Abura, Tsutomu× Fukuo, Tsuyoshi× Horiguchi, Hironobu× Matsubayashi, Gen-etsu |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26411 | |||||
| 姓名 | 荒川, 隆一 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26412 | |||||
| 姓名 | 油, 努 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26413 | |||||
| 姓名 | 福尾, 剛志 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26414 | |||||
| 姓名 | 堀口, 宏伸 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26415 | |||||
| 姓名 | 松林, 玄悦 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | An on-line electrospray ionization mass-spectrometric analysis for an electrolysis reaction was developed by the installation of a compact, efficient flow-through cell upstream of an electrospraying needle. The electrode was designed to avoid any reduction of the oxidation products formed during electrolysis. The electrolytic oxidation reaction of a Ru and Os metal complex was carried out to examine the performance of the system. From the electrolysis of [M(bpy)3](PF6)2 (where M = Ru and Os, and bpy = 2,2′-bipyridine) we detected the one-electron oxidation product, [M(bpy)3]3+. The electrolysis of [Ru(bpy)2(en)]-(ClO4)2 (en = ethylenediamine) formed two complex products along with the elimination of two and four hydrogen atoms from the en ligand. The structure of the two complex products was determined to be a monoimine and diimine complex, based on an electrolysis experiment using a deuterium-labeled complex, [Ru(bpy)2(ed)](ClO4)2 (ed = ethylene-d4-diamine, H2N–CD2–CD2–NH2). The results indicate that electrochemical oxidation occurs at the ethylenediamine ligand and that the monoimine complex is a reaction intermediate for the formation of a diimine complex. | |||||
| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 72, 号 7, p. 1519-1523, 発行日 1999 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 00092673 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00580132 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1246/bcsj.72.1519 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | Chemical Society of Japan | |||||
| 出版者（他言語） | ||||||
| 値 | 日本化学会 | |||||
