{"created":"2023-05-15T12:20:46.416998+00:00","id":11457,"links":{},"metadata":{"_buckets":{"deposit":"3a8eb4b4-461e-4b0b-9a8d-d0c0bfb1a59c"},"_deposit":{"created_by":1,"id":"11457","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11457"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011457","sets":["528:1588:1595:1597"]},"author_link":["26414","26415","26408","26407","26412","26413","26409","26406","26411","26410"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1523","bibliographicPageStart":"1519","bibliographicVolumeNumber":"72","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"An on-line electrospray ionization mass-spectrometric analysis for an electrolysis reaction was developed by the installation of a compact, efficient flow-through cell upstream of an electrospraying needle. The electrode was designed to avoid any reduction of the oxidation products formed during electrolysis. The electrolytic oxidation reaction of a Ru and Os metal complex was carried out to examine the performance of the system. From the electrolysis of [M(bpy)3](PF6)2 (where M = Ru and Os, and bpy = 2,2′-bipyridine) we detected the one-electron oxidation product, [M(bpy)3]3+. The electrolysis of [Ru(bpy)2(en)]-(ClO4)2 (en = ethylenediamine) formed two complex products along with the elimination of two and four hydrogen atoms from the en ligand. The structure of the two complex products was determined to be a monoimine and diimine complex, based on an electrolysis experiment using a deuterium-labeled complex, [Ru(bpy)2(ed)](ClO4)2 (ed = ethylene-d4-diamine, H2N–CD2–CD2–NH2). The results indicate that electrochemical oxidation occurs at the ethylenediamine ligand and that the monoimine complex is a reaction intermediate for the formation of a diimine complex.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"26411","nameIdentifierScheme":"WEKO"}],"names":[{"name":"荒川, 隆一"}]},{"nameIdentifiers":[{"nameIdentifier":"26412","nameIdentifierScheme":"WEKO"}],"names":[{"name":"油, 努"}]},{"nameIdentifiers":[{"nameIdentifier":"26413","nameIdentifierScheme":"WEKO"}],"names":[{"name":"福尾, 剛志"}]},{"nameIdentifiers":[{"nameIdentifier":"26414","nameIdentifierScheme":"WEKO"}],"names":[{"name":"堀口, 宏伸"}]},{"nameIdentifiers":[{"nameIdentifier":"26415","nameIdentifierScheme":"WEKO"}],"names":[{"name":"松林, 玄悦"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Chemical Society of Japan"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.72.1519","subitem_relation_type_select":"DOI"}}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00092673","subitem_source_identifier_type":"ISSN"}]},"item_9_text_35":{"attribute_name":"出版者（他言語）","attribute_value_mlt":[{"subitem_text_value":"日本化学会"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Arakawa, Ryuichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Abura, Tsutomu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukuo, Tsuyoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Horiguchi, Hironobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsubayashi, Gen-etsu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-19990215-13.pdf","filesize":[{"value":"726.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-19990215-13.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11457/files/KU-1100-19990215-13.pdf"},"version_id":"4cba408d-2fb9-4e20-b234-eb8087ab05cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Analysis of Electrolysis Reactions of Metal Complexes Using On-Line Electrospray Ionization Mass Spectrometry with a Compact Electrolytic Flow-Through Cell","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Analysis of Electrolysis Reactions of Metal Complexes Using On-Line Electrospray Ionization Mass Spectrometry with a Compact Electrolytic Flow-Through Cell"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-01-26"},"publish_date":"2012-01-26","publish_status":"0","recid":"11457","relation_version_is_last":true,"title":["Analysis of Electrolysis Reactions of Metal Complexes Using On-Line Electrospray Ionization Mass Spectrometry with a Compact Electrolytic Flow-Through Cell"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-05-15T18:29:11.619585+00:00"}