WEKO3
アイテム
Molecular Complexes of Hydroxy Host Systems with Alcohols. X-Ray Crystal Structures of 1,1,6,6-Tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol–Ethanol (1:2), 1,1-Bis(2,4-dimethylphenyl)-2-butyn-1-ol–Ethanol (1:1), and 9-(1-Propynyl)-9-fluorenol–Methanol (1:1)
http://hdl.handle.net/10112/5609
http://hdl.handle.net/10112/56093dd688fb-52a3-4fb6-b1a0-f96abf6c385f
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-19850800-13.pdf (975.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2011-11-21 | |||||
| タイトル | ||||||
| タイトル | Molecular Complexes of Hydroxy Host Systems with Alcohols. X-Ray Crystal Structures of 1,1,6,6-Tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol–Ethanol (1:2), 1,1-Bis(2,4-dimethylphenyl)-2-butyn-1-ol–Ethanol (1:1), and 9-(1-Propynyl)-9-fluorenol–Methanol (1:1) | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Thomas, C.W. Mak
× Thomas, C.W. Mak× Toda, Fumio× Tanaka, Koichi |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26381 | |||||
| 姓名 | 戸田, 芙三夫 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26382 | |||||
| 姓名 | 田中, 耕一 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The structures of a 1:2 molecular complex(I) of 1,1,6,6-tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol with ethanol, a 1:1 complex(II) of 1,1-bis(2,4-dimethylphenyl)-2-butyn-1-ol with ethanol, and a 1:1 complex(III) of 9-hydroxy-9-(1-propynyl)fluorene with methanol have been determined by X-ray crystallography. The crystal data are: I, C42H50O4, P\bar1, a=8.249(3), b=9.522(5), c=14.803(8)Å, α=100.95(4), β=110.82(4), γ=113.08(3)°, Z=1, and Rf=0.105 for 1834 observed Mo Kα data; II, C22H28O2, P\bar1, a=8.142(2), b=11.281(3), c=l2.262(4)Å, α=102.76(2), β=97.08(2), γ=111.19(2)°, Z=2, and Rf=0.073 for 2104 data; III, C17H16O2, P21/a, a=8.641(5), b=10.883(5), c=30.63(2)Å, β=92.88(4)°, Z=8, Rf=0.154 for 1885 data. The crystal structures of I and II are closely related and both feature planar hydrogen-bonded (OH)4 rings centered at centrosymmetric sites. In III, the fluorene and methanol molecules belong to two independent sets, and the molecular components in each set are alternately linked by hydrogen bonds to form infinite zigzag chains parallel to the a axis. | |||||
| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 58, 号 8, p. 2221-2227, 発行日 1985 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 00092673 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00580132 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1246/bcsj.58.2221 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | Chemical Society of Japan | |||||
| 出版者（他言語） | ||||||
| 値 | 日本化学会 | |||||
