{"created":"2023-05-15T12:20:46.246572+00:00","id":11453,"links":{},"metadata":{"_buckets":{"deposit":"ea391a7b-96e4-4b99-af3a-381ffe8db0b2"},"_deposit":{"created_by":1,"id":"11453","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11453"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011453","sets":["528:1588:1595:1597"]},"author_link":["26382","26381","26379","26378","26380"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"2227","bibliographicPageStart":"2221","bibliographicVolumeNumber":"58","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"The structures of a 1:2 molecular complex(I) of 1,1,6,6-tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol with ethanol, a 1:1 complex(II) of 1,1-bis(2,4-dimethylphenyl)-2-butyn-1-ol with ethanol, and a 1:1 complex(III) of 9-hydroxy-9-(1-propynyl)fluorene with methanol have been determined by X-ray crystallography. The crystal data are: I, C42H50O4, P\\bar1, a=8.249(3), b=9.522(5), c=14.803(8)Å, α=100.95(4), β=110.82(4), γ=113.08(3)°, Z=1, and Rf=0.105 for 1834 observed Mo Kα data; II, C22H28O2, P\\bar1, a=8.142(2), b=11.281(3), c=l2.262(4)Å, α=102.76(2), β=97.08(2), γ=111.19(2)°, Z=2, and Rf=0.073 for 2104 data; III, C17H16O2, P21/a, a=8.641(5), b=10.883(5), c=30.63(2)Å, β=92.88(4)°, Z=8, Rf=0.154 for 1885 data. The crystal structures of I and II are closely related and both feature planar hydrogen-bonded (OH)4 rings centered at centrosymmetric sites. In III, the fluorene and methanol molecules belong to two independent sets, and the molecular components in each set are alternately linked by hydrogen bonds to form infinite zigzag chains parallel to the a axis.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"26381","nameIdentifierScheme":"WEKO"}],"names":[{"name":"戸田, 芙三夫"}]},{"nameIdentifiers":[{"nameIdentifier":"26382","nameIdentifierScheme":"WEKO"}],"names":[{"name":"田中, 耕一"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Chemical Society of Japan"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.58.2221","subitem_relation_type_select":"DOI"}}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00092673","subitem_source_identifier_type":"ISSN"}]},"item_9_text_35":{"attribute_name":"出版者（他言語）","attribute_value_mlt":[{"subitem_text_value":"日本化学会"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Thomas, C.W. Mak"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Toda, Fumio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Koichi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-19850800-13.pdf","filesize":[{"value":"975.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-19850800-13.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11453/files/KU-1100-19850800-13.pdf"},"version_id":"07981782-0201-4973-a39e-74e10de288aa"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Molecular Complexes of Hydroxy Host Systems with Alcohols. X-Ray Crystal Structures of 1,1,6,6-Tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol–Ethanol (1:2), 1,1-Bis(2,4-dimethylphenyl)-2-butyn-1-ol–Ethanol (1:1), and 9-(1-Propynyl)-9-fluorenol–Methanol (1:1)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Molecular Complexes of Hydroxy Host Systems with Alcohols. X-Ray Crystal Structures of 1,1,6,6-Tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol–Ethanol (1:2), 1,1-Bis(2,4-dimethylphenyl)-2-butyn-1-ol–Ethanol (1:1), and 9-(1-Propynyl)-9-fluorenol–Methanol (1:1)"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-11-21"},"publish_date":"2011-11-21","publish_status":"0","recid":"11453","relation_version_is_last":true,"title":["Molecular Complexes of Hydroxy Host Systems with Alcohols. X-Ray Crystal Structures of 1,1,6,6-Tetrakis(2,4-dimethylphenyl)-2,4-hexadiyne-1,6-diol–Ethanol (1:2), 1,1-Bis(2,4-dimethylphenyl)-2-butyn-1-ol–Ethanol (1:1), and 9-(1-Propynyl)-9-fluorenol–Methanol (1:1)"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-05-15T18:29:59.858661+00:00"}