WEKO3
-
RootNode
アイテム
Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands
http://hdl.handle.net/10112/5938
http://hdl.handle.net/10112/59389217a706-d52e-4e4d-874e-8094ef5bf857
名前 / ファイル | ライセンス | アクション |
---|---|---|
![]() |
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2012-01-26 | |||||
タイトル | ||||||
タイトル | Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yamanari, Kazuaki
× Yamanari, Kazuaki× Fukuda, Ito× Yamamoto, Shiori× Kushi, Yoshihiko× Fuyuhiro, Akira× Kubota, Naoko× Fukuo, Tsuyoshi× Arakawa, Ryuichi |
|||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26894 | |||||
姓名 | 山成, 数明 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26895 | |||||
姓名 | 福田, 伊都 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26896 | |||||
姓名 | 山本, しをり | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26897 | |||||
姓名 | 久司, 佳彦 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26898 | |||||
姓名 | 冬広, 明 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26899 | |||||
姓名 | 久保田, 直子 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26900 | |||||
姓名 | 福尾, 剛志 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 26901 | |||||
姓名 | 荒川, 隆一 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Self-assembling reactions between [Rh(η5-C5Me5)(H2O)3]2+and pyrimidine-2-thionate(pymt) or related ligands [L; mpymt = 4-methyl-pyrimidine-2-thionate(1-), dmpymt = 4,6-dimethylpyrimidine-2-thionate(1-), apymt = 4-aminopyrimidine-2-thionate(1-), dapymt = 4,6-diaminopyrimidine-2-thionate(1-), or mpol = 2-sulfanyl-3-pyridinolate(2-)] were carried out and the products characterized by UV/vis, NMR spectroscopy, electrospray ionization mass spectrometry, and crystal structure analysis. All products are dinuclear rhodium(III) complexes of [{Rh(η5-C5Me5)(L)}2]n+: three crystal structures with mpymt, dmpymt and mpol were determined. The mpymt and dmpymt ligands co-ordinate through a 1κ2N,S:2κS mode and the two pyrimidine rings are located in cis position,whereas mpol adopts a five-membered chelating mode with 1κ2S,O:2κS and the two pyrimidine rings are located in trans position. Such structural difference can reasonably be explained by the intramolecular stacking interaction between the two bridging ligands. |
|||||
書誌情報 |
Journal of the Chemical Society, Dalton Transactions 巻 2000, 号 13, p. 2131-2136, 発行日 2000-01-06 |
|||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/B000098L | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry |
Share
Cite as
Yamanari, Kazuaki, Fukuda, Ito, Yamamoto, Shiori, Kushi, Yoshihiko, Fuyuhiro, Akira, Kubota, Naoko, Fukuo, Tsuyoshi, Arakawa, Ryuichi, 2000, Structural difference due to intramolecular stacking interactions in dinuclear rhodium(III) complexes [{Rh(η5-C5Me5)(L)}2]n+containing pyrimidine-2-thionate and related ligands: Royal Society of Chemistry, 2131–2136 p.
Loading...