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ビール粕炭賦活物による有機物の液相吸着
http://hdl.handle.net/10112/5512
http://hdl.handle.net/10112/55120ea9869a-6469-4393-9b35-04ce7fc93d20
名前 / ファイル | ライセンス | アクション |
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KU-1100-20060920-11.pdf (411.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-11-09 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | ビール粕炭賦活物による有機物の液相吸着 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
その他のタイトル | ||||||
その他のタイトル | Liquid-Phase Adsorption of Organic Materials with Activated Carbon Derived from Beer Lees | |||||
言語 | en | |||||
著者 |
平野, 祐樹
× 平野, 祐樹× 高坂, 智也× 中島, 慎輔× 村山, 憲弘× 芝田, 隼次× 岡本, 裕行× 木下, 宗茂 |
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概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | ビール工場から排出されるビール粕を原料として作成したビール粕炭に炭酸ガス賦活法,水蒸気賦活法,水酸化カリウム賦活法を適用し,ビール粕賦活炭を調製した.得られた3種類のビール粕賦活炭を用いてフェノール,メチレンブルー,1,2-ジクロロエタンおよび1,2-ジクロロプロパンの液相吸着特性について検討した.フェノールおよびメチレンブルーの吸着では,それぞれの吸着量は炭酸ガス賦活炭<水蒸気賦活炭<水酸化カリウム賦活炭の順に大きくなり,各種賦活炭の比表面積および全細孔容積の大きさの順と一致した.各種賦活炭のフェノールおよびメチレンブルー吸着量を比較すると,分子径の小さいフェノールの方が吸着量は大きくなった.1,2-ジクロロエタンおよび1,2-ジクロロプロパンの吸着でも同様に,それぞれの吸着量は炭酸ガス賦活炭<水蒸気賦活炭<水酸化カリウム賦活炭の順に大きくなった.各賦活炭の1,2-ジクロロエタンおよび1,2-ジクロロプロパン吸着量を比較すると,両化合物の分子サイズは類似しているにも関わらず,1,2-ジクロロプロパンの吸着量が1,2-ジクロロエタンの2倍以上となった.この相違は,両化合物の水に対する溶解度の違いに基づくものと考えられる.溶解度の大きい1,2-ジクロロエタンは溶媒中により安定に存在するため,吸着量が小さくなったと考えられる. | |||||
言語 | ja | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Three activation methods, CO2 activation, steam activation and KOH activation, were used to activate beer lees charcoal manufactured from beer lees discharged by a brewery. Liquid-phase adsorption properties of phenol, methylene blue, 1,2-dichloroethane and 1,2-dichloropropane by the resulting activated charcoal were examined.The amounts of phenol and methylene blue adsorbed were found to increase in the order CO2 activated charcoal<steam activated charcoal<KOH activated charcoal. This order coincides with the order of their pore volume of the charcoals. Phenol was adsorbed in a larger amount than methylene blue on all charcoals, probably because of its smaller molecular size. The same order of performance was found for the adsorption of 1,2-dichloroethane and 1,2-dichloropropane: CO2 activated charcoal<steam activated charcoal<KOH activated charcoal. The amount of 1,2-dichloropropane adsorbed was twice that of 1,2-dichloroethane, even though they have similar molecular sizes. This is thought to be due to higher solubility of 1,2-dichloroethane in water, which would reflect its higher affinity for water molecules and make it more difficult to be captured by adsorbent. | |||||
言語 | en | |||||
書誌情報 |
ja : 化学工学論文集 巻 32, 号 5, p. 448-453, 発行日 2006-09-20 |
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ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0386216X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00037234 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
言語 | ja | |||||
出版者 | 化学工学会 | |||||
キーワード | ||||||
言語 | ja | |||||
主題Scheme | Other | |||||
主題 | ビール粕 | |||||
キーワード | ||||||
言語 | ja | |||||
主題Scheme | Other | |||||
主題 | 賊活 | |||||
キーワード | ||||||
言語 | ja | |||||
主題Scheme | Other | |||||
主題 | 活性炭 | |||||
キーワード | ||||||
言語 | ja | |||||
主題Scheme | Other | |||||
主題 | 有害有機物 | |||||
キーワード | ||||||
言語 | ja | |||||
主題Scheme | Other | |||||
主題 | 液相吸着 | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Beer Less | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Activation | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Activated Carbon | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Harmful Organic Material | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Liquid-Phase Adsorption |