{"created":"2023-05-15T12:20:39.710510+00:00","id":11306,"links":{},"metadata":{"_buckets":{"deposit":"159cf27b-af77-4828-9a2f-f083ecc6c4e5"},"_deposit":{"created_by":1,"id":"11306","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11306"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011306","sets":["528:1588:1592:1594"]},"author_link":["25382","25383","25384","25385","25386","25387","25388"],"control_number":"11306","item_9_alternative_title_20":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Liquid-Phase Adsorption of Organic Materials with Activated Carbon Derived from Beer Lees","subitem_alternative_title_language":"en"}]},"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-09-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"453","bibliographicPageStart":"448","bibliographicVolumeNumber":"32","bibliographic_titles":[{"bibliographic_title":"化学工学論文集","bibliographic_titleLang":"ja"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"ビール工場から排出されるビール粕を原料として作成したビール粕炭に炭酸ガス賦活法，水蒸気賦活法，水酸化カリウム賦活法を適用し，ビール粕賦活炭を調製した．得られた3種類のビール粕賦活炭を用いてフェノール，メチレンブルー，1,2-ジクロロエタンおよび1,2-ジクロロプロパンの液相吸着特性について検討した．フェノールおよびメチレンブルーの吸着では，それぞれの吸着量は炭酸ガス賦活炭<水蒸気賦活炭<水酸化カリウム賦活炭の順に大きくなり，各種賦活炭の比表面積および全細孔容積の大きさの順と一致した．各種賦活炭のフェノールおよびメチレンブルー吸着量を比較すると，分子径の小さいフェノールの方が吸着量は大きくなった．1,2-ジクロロエタンおよび1,2-ジクロロプロパンの吸着でも同様に，それぞれの吸着量は炭酸ガス賦活炭<水蒸気賦活炭<水酸化カリウム賦活炭の順に大きくなった．各賦活炭の1,2-ジクロロエタンおよび1,2-ジクロロプロパン吸着量を比較すると，両化合物の分子サイズは類似しているにも関わらず，1,2-ジクロロプロパンの吸着量が1,2-ジクロロエタンの2倍以上となった．この相違は，両化合物の水に対する溶解度の違いに基づくものと考えられる．溶解度の大きい1,2-ジクロロエタンは溶媒中により安定に存在するため，吸着量が小さくなったと考えられる．","subitem_description_language":"ja","subitem_description_type":"Other"},{"subitem_description":"Three activation methods, CO2 activation, steam activation and KOH activation, were used to activate beer lees charcoal manufactured from beer lees discharged by a brewery. Liquid-phase adsorption properties of phenol, methylene blue, 1,2-dichloroethane and 1,2-dichloropropane by the resulting activated charcoal were examined.The amounts of phenol and methylene blue adsorbed were found to increase in the order CO2 activated charcoal<steam activated charcoal<KOH activated charcoal. This order coincides with the order of their pore volume of the charcoals. Phenol was adsorbed in a larger amount than methylene blue on all charcoals, probably because of its smaller molecular size. The same order of performance was found for the adsorption of 1,2-dichloroethane and 1,2-dichloropropane: CO2 activated charcoal<steam activated charcoal<KOH activated charcoal. The amount of 1,2-dichloropropane adsorbed was twice that of 1,2-dichloroethane, even though they have similar molecular sizes. This is thought to be due to higher solubility of 1,2-dichloroethane in water, which would reflect its higher affinity for water molecules and make it more difficult to be captured by adsorbent.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"化学工学会","subitem_publisher_language":"ja"}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00037234","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0386216X","subitem_source_identifier_type":"PISSN"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"平野, 祐樹","creatorNameLang":"ja"},{"creatorName":"Hirano, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"高坂, 智也","creatorNameLang":"ja"},{"creatorName":"Kousaka, Tomoya","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"中島, 慎輔","creatorNameLang":"ja"},{"creatorName":"Nakajima, Shinsuke","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"村山, 憲弘","creatorNameLang":"ja"},{"creatorName":"Murayama, Norihiro","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"芝田, 隼次","creatorNameLang":"ja"},{"creatorName":"Shibata, Junji","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"岡本, 裕行","creatorNameLang":"ja"},{"creatorName":"Okamoto, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"木下, 宗茂","creatorNameLang":"ja"},{"creatorName":"Kinoshita, Muneshige","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20060920-11.pdf","filesize":[{"value":"411.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20060920-11.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11306/files/KU-1100-20060920-11.pdf"},"version_id":"4539d185-d8a1-4a48-8efb-74a28935ebf9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ビール粕","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"賊活","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"活性炭","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"有害有機物","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"液相吸着","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Beer Less","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Activation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Activated Carbon","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Harmful Organic Material","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Liquid-Phase Adsorption","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ビール粕炭賦活物による有機物の液相吸着","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ビール粕炭賦活物による有機物の液相吸着","subitem_title_language":"ja"}]},"item_type_id":"9","owner":"1","path":["1594"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2011-11-09"},"publish_date":"2011-11-09","publish_status":"0","recid":"11306","relation_version_is_last":true,"title":["ビール粕炭賦活物による有機物の液相吸着"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-10-27T01:56:13.941234+00:00"}