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Hydrothermal synthesis of potassium-type zeolite from coal fly ash and evaluation of its physical properties
http://hdl.handle.net/10112/6406
http://hdl.handle.net/10112/64069ee72333-e28a-4ece-b6aa-09d535c23a2c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-20050000-06.pdf (631.2 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2012-04-13 | |||||
| タイトル | ||||||
| タイトル | Hydrothermal synthesis of potassium-type zeolite from coal fly ash and evaluation of its physical properties | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
Takahashi, Tomoya
× Takahashi, Tomoya× Murayama, Norihiro× Yamamoto, Hideki× Shibata, Junji |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 28107 | |||||
| 姓名 | 高橋, 智哉 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 28108 | |||||
| 姓名 | 村山, 憲弘 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 28109 | |||||
| 姓名 | 山本, 秀樹 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 28110 | |||||
| 姓名 | 芝田, 隼次 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Hydrothermal syntheses of potassium-type zeolite from coal fly ash were carried out under various KOH concentrations and reaction temperatures, and crystal structure and cation exchange capacity (CEC) of the reaction products were investigated. Both acid resistance and heat resistance of the reaction products were considered, as these are important for use as a cation exchanger,a catalyst or an absorbent. When hydrothermal synthesis from coal fly ash is conducted at a reaction temperature of 393K, potassium chabazite (K-CHA) begins to form for 5h of reaction time. K-CHA and K-H zeolite are formed as zeolite species at 393K and 453K,respectively. Both K-CHA and K-H zeolite are synthesized simultaneously at 433K. CEC values of the obtained K-CHA and K-H zeolite are 208meq/100g and 104meq/ 100g. respectively. The CEC of reaction products decreases with increasing reaction temperature, and this phenomenon dictates the kind of formed zeolite. X-ray diffraction intensities of K-CHA gradually decrease with decreasing pH in the range above pH4. Whereas, in the range below pH 4, this intensity decreases rapidly and the elution amount of Al3+ from K-CHA with proton increases remarkably. In the case of heat treatment below 873K, the X-ray diffraction intensity of K-CHA decreases with increasing calcined temperature, but thermal decomposition of K-CHA and production of new crystalline materials do not take place in these treatments. With a heat treatment of 1273K,the K-CHA peaks disappear in the XRD pattern, and those of leucite generate anew. |
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| 書誌情報 |
関西大学工学研究報告 = Technology reports of the Kansai University 巻 47, p. 11-20, 発行日 2005-03-21 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 04532198 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00046916 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 関西大学工学部 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | hydrothermal synthesis | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | zeolite | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | coal fly ash | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cation exchange capacity | |||||
