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Analysis of Photochemical Reactions of Bis(1,10-phenthroline)-diamineruthenium(II) Complexes by Electrospray Ionization Mass Spectrometry
http://hdl.handle.net/10112/5992
http://hdl.handle.net/10112/599254793f74-9baa-43cd-8f52-a17590dbc7e8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-20010000-02.pdf (438.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2012-02-02 | |||||
| タイトル | ||||||
| タイトル | Analysis of Photochemical Reactions of Bis(1,10-phenthroline)-diamineruthenium(II) Complexes by Electrospray Ionization Mass Spectrometry | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Arakawa, Ryuichi
× Arakawa, Ryuichi× Abe, Kazuyuki× Iwai, Masayoshi× Fukuo, Tsuyoshi× Nakabayashi, Yasuo |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26995 | |||||
| 姓名 | 荒川, 隆一 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26996 | |||||
| 姓名 | 阿部, 一之 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26997 | |||||
| 姓名 | 岩井, 正宣 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26998 | |||||
| 姓名 | 福尾, 剛志 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26999 | |||||
| 姓名 | 中林, 安雄 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The photo ligand substitution reaction of the bisphenanthroline complex [Ru(phen)2B]2+ (where phen=1,10-phenanthroline, B=ethylenediamine (en), trimethylenediamine (tn), or butanediamine (bn)) in acetonitrile solution was studied using electrospray ionization mass spectrometry (ESI-MS). The photochemical reaction of a diamineruthenium(II) complex has been known to proceed by oxidation of a diamine ligand to an α,α′-diimine by oxidative dehydrogenation. The final reaction product was a solvent substituted complex [Ru(phen)2S2]2+, where S is the solvent acetonitrile. We detected two monodentate complexes, an imine complex [Ru(phen)2(B-2)S]2+ and a nitroso complex [Ru(phen)2(en+14)S]2+ in the ESI-MS analysis of the photoreaction products of [Ru(phen)2B]2+. These monodentate complexes were not observed with a bipyridine complex [Ru(bpy)2B]2+ (where bpy=2,2′-bipyridine, B=en or tn). In addition, photochemical reactivity of the phen complex was found to be higher than that of the bpy complex. The difference in the photochemical reactivity can be explained by the difference in configurational flexibility of the phen and bpy ligands in the ruthenium complexes. | |||||
| 書誌情報 |
Journal of the Mass Spectrometry Society of Japan 巻 49, 号 5, p. 183-187, 発行日 2001 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 13408097 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA1254271X | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.5702/massspec.49.183 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | Mass Spectrometry Society of Japan | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | ESI-MS | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Photochemical reactions | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Bis(1, 10-phen-anthroline)diamineruthenium(II)complexes | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Intermediate | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | MLCT | |||||
| 出版者（他言語） | ||||||
| 値 | 日本質量分析学会 | |||||
