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Detection of Polynuclear Zirconium Hydroxide Species in Aqueous Solution by Desktop ESI-MS
http://hdl.handle.net/10112/5936
http://hdl.handle.net/10112/5936ee1ec73c-2d3e-4bab-9c8e-77badee6e2d3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-20100410-13.pdf (450.0 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2012-01-26 | |||||
| タイトル | ||||||
| タイトル | Detection of Polynuclear Zirconium Hydroxide Species in Aqueous Solution by Desktop ESI-MS | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Sasaki, Takayuki
× Sasaki, Takayuki× Nakaoka, Osamu× Arakawa, Ryuichi× Kobayashi, Taishi× Takagi, Ikuji× Moriyama, Hirotake |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26840 | |||||
| 姓名 | 佐々木, 隆之 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26841 | |||||
| 姓名 | 中岡, 平 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26842 | |||||
| 姓名 | 荒川, 隆一 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26843 | |||||
| 姓名 | 小林, 大志 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26844 | |||||
| 姓名 | 高木, 郁二 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26845 | |||||
| 姓名 | 森山, 裕丈 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The direct detection of polymerized tetravalent zirconium hydroxides was performed by using a commercially available desktop electrospray ionization mass spectrometry device equipped with a nanospray capillary heated at 90℃. It was confirmed that the abundance ratio of the species did not depend significantly on the desolvation line temperature up to 170℃. Under the acidic pH condition, the positively charged polymers up to 12-mer species of zirconium were assigned based on the m/z values and the natural abundance isotopic compositions of Zr and Cl. The distribution of the species was observed to change depending on the pH value and the aging period. The hydrolysis constants for the polynuclear species predominantly formed in a solution were estimated from the results of the analysis of the observed spectra with the help of an electrostatic hard sphere model. The obtained values were found to be comparable with the literature ones. |
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| 書誌情報 |
JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY 巻 47, 号 12, p. 1211-1218, 発行日 2010 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 00223131 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00703720 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1080/18811248.2010.9720988 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | Atomic Energy Society of Japan | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | zirconium | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | polymer | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | ESI-MS | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | hydrolysis constants | |||||
| 出版者（他言語） | ||||||
| 値 | 日本原子力学会 | |||||
