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Studies on metal-ion complex formation of crown ether derivatives incorporating a photoionizable spirobenzopyran moiety by electrospray ionization mass spectrometry
http://hdl.handle.net/10112/5930
http://hdl.handle.net/10112/5930c29575ca-cdde-481a-a158-e9ea57d80d18
名前 / ファイル | ライセンス | アクション |
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KU-1100-20000522-01.pdf.pdf (430.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-01-26 | |||||
タイトル | ||||||
タイトル | Studies on metal-ion complex formation of crown ether derivatives incorporating a photoionizable spirobenzopyran moiety by electrospray ionization mass spectrometry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kimura, Keiichi
× Kimura, Keiichi× Sakamoto, Hidefumi× Kado, Shinpei× Arakawa, Ryuichi× Yokoyama, Masaaki |
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著者別名 | ||||||
姓名 | 木村, 恵一 | |||||
著者別名 | ||||||
姓名 | 坂本, 英文 | |||||
著者別名 | ||||||
姓名 | 門, 晋平 | |||||
著者別名 | ||||||
姓名 | 荒川, 隆一 | |||||
著者別名 | ||||||
姓名 | 横山, 正明 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Metal-ion complexation of crown ether derivatives incorporating one and two spirobenzopyran units was investigated by electrospray ionization mass spectrometry.The crowned spirobenzopyran derivatives exhibited very different metal ion-complexing behavior from their corresponding parent crown ether rings,preferring multivalent to monovalent metal ions owing to the additional ionic interaction with the nitrophenolate anion of the merocyanine moiety.The on-line photochemical reaction for mass spectrometry indicated that the metal ion-complexing ability and ion selectivities of the crowned spirobenzopyrans can be switched photochemically,taking advantage of the difference between the spiropyran and merocyanine isomers. | |||||
書誌情報 |
Analyst 巻 125, p. 1091-1095, 発行日 2000-05-22 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00032654 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00524823 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/b002215m | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry |