{"created":"2023-05-15T12:29:27.440549+00:00","id":23353,"links":{},"metadata":{"_buckets":{"deposit":"c9ce532b-d26b-46cf-8e2f-4cee41b805da"},"_deposit":{"created_by":10,"id":"23353","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"23353"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00023353","sets":["528:1588:1595:1597","63:71"]},"author_link":["52044","52041","52039","52046","52036","52051","52047","52037","52049","52042","52048","52038","52040","52050","52045","52043"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-18","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"210","bibliographicPageStart":"192","bibliographicVolumeNumber":"97","bibliographic_titles":[{"bibliographic_title":"Heterocycles"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Using a novel tandem reduction-cyclization, we synthesized t-butyl 3-alkyloxindole-3-carboxylates from the di-t-butyl 2-alkyl-2-(2-nitrophenyl)malonate. Introduction of an α-substituent to the di-t-butyl 2-(2-nitrophenyl)-malonates and addition of acid promoted reactivity. This methodology was successfully applied to gram-scale-synthesis of the t-butyl 3-methyloxindole-3-carboxylate 1 and 3-hydroxymethyl-3-methyloxindole 2 without silica gel column chromatography.","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Part of this work was supported by the Kansai University Subsidy for Supporting Young Scholars, 2015 “Development of macrocyclization reaction via a photoaffinity reaction”, JSPS KAKENHI Grant Number 15K18903, Grant-in-Aid for Young Scientists (B) – Japan and MEXT – Supported Program for the Strategic Research Foundation at Private Universities (2013–2017) – Japan.","subitem_description_type":"Other"},{"subitem_description":"2015年度関西大学若手研究者育成経費","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"52044","nameIdentifierScheme":"WEKO"}],"names":[{"name":"山井, 悠介"}]},{"nameIdentifiers":[{"nameIdentifier":"52045","nameIdentifierScheme":"WEKO"}],"names":[{"name":"田中, 章夫"}]},{"nameIdentifiers":[{"nameIdentifier":"52046","nameIdentifierScheme":"WEKO"}],"names":[{"name":"矢島, 辰雄"}]},{"nameIdentifiers":[{"nameIdentifier":"52047","nameIdentifierScheme":"WEKO"}],"names":[{"name":"石田, 恭次"}]},{"nameIdentifiers":[{"nameIdentifier":"52048","nameIdentifierScheme":"WEKO"}],"names":[{"name":"夏谷, 格"}]},{"nameIdentifiers":[{"nameIdentifier":"52049","nameIdentifierScheme":"WEKO"}],"names":[{"name":"上里, 新一"}]},{"nameIdentifiers":[{"nameIdentifier":"52050","nameIdentifierScheme":"WEKO"}],"names":[{"name":"長岡, 康夫"}]},{"nameIdentifiers":[{"nameIdentifier":"52051","nameIdentifierScheme":"WEKO"}],"names":[{"name":"住吉, 孝明"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic Chemistry"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/COM-17-S(T)2","subitem_relation_type_select":"DOI"}}]},"item_9_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 The Japan Institute of Heterocyclic Chemistry"},{"subitem_rights":"この論文は日本複素環化学研究所の許諾を得て公開しています。"}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855414","subitem_source_identifier_type":"ISSN"}]},"item_9_text_35":{"attribute_name":"出版者（他言語）","attribute_value_mlt":[{"subitem_text_value":"日本複素環化学研究所"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamai, Yu-suke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Akio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yajima, Tatsuo"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Ishida, Kyoji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Natsutani, Itaru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Uesato, Shinichi"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Nagaoka, Yasuo"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Sumiyoshi, Takaaki"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-10-13"}],"displaytype":"detail","filename":"KU-0020-20171218-01.pdf","filesize":[{"value":"913.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-0020-20171218-01.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/23353/files/KU-0020-20171218-01.pdf"},"version_id":"58cf9410-faaf-4b46-82ea-7e1bc6a2aba8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"process chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"3,3-disubstituted oxindole","subitem_subject_scheme":"Other"},{"subitem_subject":"x-ray crystal analysis","subitem_subject_scheme":"Other"},{"subitem_subject":"DFT calculation","subitem_subject_scheme":"Other"},{"subitem_subject":"tandem reduction-cyclizationプロセス化学","subitem_subject_scheme":"Other"},{"subitem_subject":"3,3-二置換オキシインドール","subitem_subject_scheme":"Other"},{"subitem_subject":"X線結晶解析","subitem_subject_scheme":"Other"},{"subitem_subject":"DFT計算","subitem_subject_scheme":"Other"},{"subitem_subject":"タンデム型還元環化反応","subitem_subject_scheme":"Other"},{"subitem_subject":"関西大学","subitem_subject_scheme":"Other"},{"subitem_subject":"Kansai University","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"SYNTHESIS OF SUBSTITUTED t-BUTYL 3-ALKYLOXINDOLE-3-CARBOXYLATES FROM DI-t-BUTYL (2-NITROPHENYL)MALONATES","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"SYNTHESIS OF SUBSTITUTED t-BUTYL 3-ALKYLOXINDOLE-3-CARBOXYLATES FROM DI-t-BUTYL (2-NITROPHENYL)MALONATES"}]},"item_type_id":"9","owner":"10","path":["71","1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-10-13"},"publish_date":"2022-10-13","publish_status":"0","recid":"23353","relation_version_is_last":true,"title":["SYNTHESIS OF SUBSTITUTED t-BUTYL 3-ALKYLOXINDOLE-3-CARBOXYLATES FROM DI-t-BUTYL (2-NITROPHENYL)MALONATES"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-05-15T16:19:09.233663+00:00"}