@article{oai:kansai-u.repo.nii.ac.jp:02000640, author = {Goto, Masahide and 後藤, 誠英 and Nakaoka, Marina and 中岡, 珠菜 and Nagata, Tatsuki and 永田, 達己 and Suzuki, Takeyuki and 鈴木, 健之 and 川﨑, 英也 and Kawasaki, Hideya and 大洞, 康嗣 and Obora, Yasushi and 曽川, 洋光 and Sogawa, Hiromitsu and 三田, 文雄 and Sanda, Fumio}, issue = {6}, journal = {Journal of network polymer, Japan = ネットワークポリマー論文集}, month = {Nov}, note = {Poly(4-ethynylaniline) [poly(1)] coordinated to palladium nanoclusters (Pd NCs) were prepared. The coordination of Pd NCs was confirmed by X-ray photoelectron spectroscopy and scanning transmission electron microscopy. Pd NCs were coordinated with the benzene rings as well as amino groups of poly(1). Pd NCs were partly coordinated with the polymers, maintaining their original size, and formed aggregates with sizes of several tens-hundreds nanometers. Poly(1) coordinated to Pd NCs efficiently served as catalysts for the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions., This is a product of research which was financially supported in part by the Kansai University Fund for the Promotion and Enhancement of Education and Research, 2023. "Development of Materials Featuring Innovative Catalytic and Photoelectric Functions Based on Cooperation of Metal Nanoclusters and π-Conjugated Polymers". 研究課題「金属ナノクラスターと共役高分子の協調による革新的触媒・光電気機能材料開発」}, pages = {1--32}, title = {Preparation and Catalytic Function of Substituted Polyacetylenes Coordinated to Palladium Nanoclusters}, volume = {44}, year = {2023} }