{"created":"2023-09-13T01:59:39.417796+00:00","id":2000237,"links":{},"metadata":{"_buckets":{"deposit":"15904b21-ebfa-48f1-b716-2e55e1641047"},"_deposit":{"created_by":10,"id":"2000237","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"2000237"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:02000237","sets":["85:92:102:1816:106"]},"author_link":["2290"],"control_number":"2000237","item_10_alternative_title_20":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Characterization of Organic Binding Media Used in Egyptian Painting Layers by GC-MS","subitem_alternative_title_language":"en"}]},"item_10_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-03-04","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"214","bibliographicPageStart":"207","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"Semawy Menu"}]}]},"item_10_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"In the colorful Egyptian wall paintings, the color materials were fixed using organic binding media so as not to exfoliate from the wall painting surface. The aim of this study is to investigate the possibility of discrimination between gum arabic and animal protein-based binders used in ancient wall paintings in the mastaba of Idout, Saqqara and to recognize the mixtures of the two products. In the present study, three methods of sample preparation and injection in gas chromatograph-mass spectrometry (GC/MS) were used. The three methods: liquid injection, pyrolysis (Py), and thermally assisted hydrolysis and methylation (THM), were tested for the most highly sensitive detection of the organic binding media. The GC/MS results showed that the liquid injection could not detect the natural products, but Py-GC/MS method was detected hydrocarbon and pyrrol, and THM-GC/MS method was detected fatty-acid methyl esters. It was found that the samples include much lauric acid methyl ester and myristic acid methyl ester. These suggested that the mixture of wax and animal glue was used as the organic binding media.","subitem_description_language":"en","subitem_description_type":"Other"},{"subitem_description":"サッカラのイドゥートの埋葬室の壁画に使用されている接着成分の識別を目指し、ガスクロマトグラフィー質量分析(GC/MS)の3種類の測定手法、液体注入法、熱分解法および反応熱分解法を用いて、壁画表面の有機化合物の分析を行った。液体注入法では天然物由来の有機化合物はほとんど検出されなかったが、熱分解法(Py-GC/MS)ではハイドロカーボンやピロロールなどが検出され、反応熱分解法(THM-GC/MS)からモノカルボン酸(特にラウリル酸、ミリスチン酸が)やジカルボン酸などの脂肪酸がメチルエステル化されて検出した。これらの結果から蝋や動物性の膠が接着成分として使用されていることが示唆された。","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.32286/0002000237","subitem_identifier_reg_type":"JaLC"}]},"item_10_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"関西大学文化財保存修復研究拠点","subitem_publisher_language":"ja"},{"subitem_publisher":"Institute for Conservation and Restoration of Cultural Properties, Kansai University","subitem_publisher_language":"en"}]},"item_10_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"BB04028363","subitem_source_identifier_type":"NCID"}]},"item_10_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山田, 陽香","creatorNameLang":"ja"},{"creatorName":"Yamada, Haruka","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"浅井, 重博","creatorNameLang":"ja"},{"creatorName":"Asai, Shigehiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"久富, 広隆","creatorNameLang":"ja"},{"creatorName":"Hisatomi, Hirotaka","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"シュエイブ, アフメド","creatorNameLang":"ja"},{"creatorName":"Shoeib, Ahmed S.","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"川崎, 英也","creatorNameLang":"ja"},{"creatorName":"Kawasaki, Hideya","creatorNameLang":"en"}],"familyNames":[{"familyName":"川崎","familyNameLang":"ja"},{"familyName":"Kawasaki","familyNameLang":"en"}],"givenNames":[{"givenName":"英也","givenNameLang":"ja"},{"givenName":"Hideya","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"2290","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50322285","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000050322285"},{"nameIdentifier":"0000-0003-2713-2057","nameIdentifierScheme":"ORCID iD","nameIdentifierURI":"https://orcid.org/0000-0003-2713-2057"}]},{"creatorNames":[{"creatorName":"吹田, 浩","creatorNameLang":"ja"},{"creatorName":"Suita, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"80247890","nameIdentifierScheme":"e-Rad_Researcher","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000080247890"}]},{"creatorNames":[{"creatorName":"荒川, 隆一","creatorNameLang":"ja"},{"creatorName":"Arakawa, Ryuichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"00127177","nameIdentifierScheme":"e-Rad_Researcher","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000000127177"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-09-06"}],"displaytype":"detail","filename":"KU-0040-20130304-18.pdf","format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://kansai-u.repo.nii.ac.jp/record/2000237/files/KU-0040-20130304-18.pdf"},"version_id":"ae2edd1c-6cae-4a7b-a295-f8795712c869"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"エジプト","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"サッカラ","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"文化財","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"修復","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"関西大学","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Kansai University","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ガスクロマトグラフ質量分析によるエジプト墜画中の有機化合物の分析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ガスクロマトグラフ質量分析によるエジプト墜画中の有機化合物の分析","subitem_title_language":"ja"}]},"item_type_id":"10","owner":"10","path":["106"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-09-06"},"publish_date":"2023-09-06","publish_status":"0","recid":"2000237","relation_version_is_last":true,"title":["ガスクロマトグラフ質量分析によるエジプト墜画中の有機化合物の分析"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2024-10-30T02:52:10.113332+00:00"}