{"created":"2023-05-15T12:20:53.310084+00:00","id":11603,"links":{},"metadata":{"_buckets":{"deposit":"d57fda08-de13-424a-9d10-cb213b12cf8e"},"_deposit":{"created_by":1,"id":"11603","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11603"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011603","sets":["528:1588:1595:1597"]},"author_link":["27537","27539","27535","27536","27534","27538"],"item_9_alternative_title_20":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Determination of 1,3-butadiene dicarbonate produced by supercritical reactions using electrospray lonization mass spectrometry"}]},"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-06-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"546","bibliographicPageStart":"541","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"分析化学"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"超臨界反応による1,3-butadiene diepoxide(BDE)から1,3-butadiene dicarbonate(BDC)へのCO_2導入反応を行った.エレクトロスプレーイオン化質量分析法(ESI-MS)により,反応生成物はアルカリ金属付加イオンとして検出できた.アルカリ金属塩の触媒効果を測定し,NaIが最も高い触媒活性を示した.その触媒の効果は,アルカリ金属原子とハロゲン原子のイオン半径差,又はハロゲンの電気陰性度の差に依存していること分かった.これらBDCなどのカーボネート化合物の分析にESI-MSが有効であることが分かった.\n\\nThe introduction reaction of carbon dioxide from 1,3-butadiene diepoxide to 1,3-butadiene dicarbonate was studied using catalysts of various alkali halides in supercritical carbon dioxide(scCO_2). The reaction products were analyzed by electrospray ionization mass spectrometry(ESI-MS); also, the catalytic effect of alkali halides was examined. The results indicated that sodium iodide had the greatest catalytic effect among them. A tendency of the effect was considered based on the difference in the ion radius between alkaline metal and halogen, or the difference in the electronegativity of halogens. ESI-MS was a useful technique to analyze carbonate compounds formed by the scCO_2 reaction.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"27537","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Uemura, Seiji"}]},{"nameIdentifiers":[{"nameIdentifier":"27538","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Abe, Kazuyuki"}]},{"nameIdentifiers":[{"nameIdentifier":"27539","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Arakawa, Ryuichi"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05251931","subitem_source_identifier_type":"ISSN"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"植村, 誠治"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"阿部, 一之"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"荒川, 隆一"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20040605-06.pdf","filesize":[{"value":"654.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20040605-06.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11603/files/KU-1100-20040605-06.pdf"},"version_id":"317eb464-c408-4d69-ba6c-2f01080121e9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"electrospray ionization mass spectrometry","subitem_subject_scheme":"Other"},{"subitem_subject":"supercritical carbon dioxide","subitem_subject_scheme":"Other"},{"subitem_subject":"1,3-butadiene diepoxide","subitem_subject_scheme":"Other"},{"subitem_subject":"1,3-butadience dicarbonate","subitem_subject_scheme":"Other"},{"subitem_subject":"catalysis of alkali halides","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-02-02"},"publish_date":"2012-02-02","publish_status":"0","recid":"11603","relation_version_is_last":true,"title":["エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T19:14:39.230955+00:00"}