@article{oai:kansai-u.repo.nii.ac.jp:00011603,
 author = {植村, 誠治 and 阿部, 一之 and 荒川, 隆一},
 issue = {6},
 journal = {分析化学},
 month = {Jun},
 note = {超臨界反応による1,3-butadiene diepoxide(BDE)から1,3-butadiene dicarbonate(BDC)へのCO_2導入反応を行った.エレクトロスプレーイオン化質量分析法(ESI-MS)により,反応生成物はアルカリ金属付加イオンとして検出できた.アルカリ金属塩の触媒効果を測定し,NaIが最も高い触媒活性を示した.その触媒の効果は,アルカリ金属原子とハロゲン原子のイオン半径差,又はハロゲンの電気陰性度の差に依存していること分かった.これらBDCなどのカーボネート化合物の分析にESI-MSが有効であることが分かった.
\nThe introduction reaction of carbon dioxide from 1,3-butadiene diepoxide to 1,3-butadiene dicarbonate was studied using catalysts of various alkali halides in supercritical carbon dioxide(scCO_2). The reaction products were analyzed by electrospray ionization mass spectrometry(ESI-MS); also, the catalytic effect of alkali halides was examined. The results indicated that sodium iodide had the greatest catalytic effect among them. A tendency of the effect was considered based on the difference in the ion radius between alkaline metal and halogen, or the difference in the electronegativity of halogens. ESI-MS was a useful technique to analyze carbonate compounds formed by the scCO_2 reaction.},
 pages = {541--546},
 title = {エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量},
 volume = {53},
 year = {2004}
}