{"created":"2023-05-15T12:20:51.046569+00:00","id":11558,"links":{},"metadata":{"_buckets":{"deposit":"d8f148f6-cc9f-4038-8b7e-9c8f5d0f7d4f"},"_deposit":{"created_by":1,"id":"11558","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11558"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011558","sets":["528:1588:1595:1597"]},"author_link":["27221","27219","27222","27218"],"item_9_alternative_title_20":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis and Thermal Properties of Curing Materials by Thermosetting Epoxy Resins with ε-Caprolactam"}]},"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"85","bibliographicPageStart":"81","bibliographicVolumeNumber":"38","bibliographic_titles":[{"bibliographic_title":"ネットワークポリマー＝Nettwork Polymer"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"ε-カプロラクタム(CL)と様々なタイプのエポキシ樹脂類、ビフェニル型(YX-4000、NC-3000)、ノボラック樹脂型(N500P-1、EPPN-502H)、グリシジルアミン型(EP630）との熱硬化反応を検討した。仕込み比、CL/エポキシ樹脂類 = 10/2～10/20の範囲で、ジアザビシクロウンデセン(DBU)存在下、80～170℃、2時間の範囲で加熱したところ、EPPN-502H以外のすべてのエポキシ樹脂類において、対応する架橋硬化物が定量的に得られた。さらに得られた硬化物のガラス転移温度(Tg)と熱重量損失温度(Tdi)を測定した結果、Tg = 121 - 232℃、Tdi = 321～360℃の範囲であることが分かり、得られた架橋硬化物は高いTgと高い耐熱性を有することが判明した。","subitem_description_type":"Other"},{"subitem_description":"We examined thermal curing reaction of various epoxy resins with ɛ-caprolactam (ɛ-CL). The reactions of epoxy resins andn ɛ-CL were carried out in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in the range between 80 and 170℃ for 2 h, the anionic ring-opening copolymerization proceeded to give corresponding cured products quantitatively. The glass transition temperatures and thermal stabilities of the obtained cured materials were determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), and each of them showed a high glass transition temperatures and high thermal stabilities.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"27221","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Buya, Kentaro"}]},{"nameIdentifiers":[{"nameIdentifier":"27222","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kudo, Hiroto"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"合成樹脂工業協会"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.11364/networkpolymer.38.81","subitem_relation_type_select":"DOI"}}]},"item_9_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C)合成樹脂工業協会;このデータはネットワークポリマー編集委員会より許諾を得て公開しています。"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2186537X","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"13420577","subitem_source_identifier_type":"ISSN"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"歩谷, 健太郎"}],"nameIdentifiers":[{"nameIdentifier":"27218","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"工藤, 宏人","creatorNameLang":"ja"},{"creatorName":"Kudo, Hiroto","creatorNameLang":"en"}],"familyNames":[{"familyName":"工藤","familyNameLang":"ja"},{"familyName":"Kudo","familyNameLang":"en"}],"givenNames":[{"givenName":"宏人","givenNameLang":"ja"},{"givenName":"Hiroto","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"27219","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30343635","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000030343635"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20170400-00.pdf","filesize":[{"value":"275.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20170400-00.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11558/files/KU-1100-20170400-00.pdf"},"version_id":"32758bc9-5c9d-4618-9791-098549b74cb6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ɛ-caprolactam","subitem_subject_scheme":"Other"},{"subitem_subject":"epoxy resin","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal curing reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"anionic ring-opening polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"関西大学","subitem_subject_scheme":"Other"},{"subitem_subject":"Kansai University","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ε-カプロラクタムとエポキシ樹脂類の熱硬化反応と得られた架橋硬化物の性質","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ε-カプロラクタムとエポキシ樹脂類の熱硬化反応と得られた架橋硬化物の性質"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-09-03"},"publish_date":"2018-09-03","publish_status":"0","recid":"11558","relation_version_is_last":true,"title":["ε-カプロラクタムとエポキシ樹脂類の熱硬化反応と得られた架橋硬化物の性質"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2024-05-28T02:47:10.257952+00:00"}