@article{oai:kansai-u.repo.nii.ac.jp:00011533,
 author = {Okuno, Shoji and Arakawa, Ryuichi and Wada, Yoshinao},
 issue = {1},
 journal = {Journal of the Mass Spectrometry Society of Japan},
 month = {},
 note = {Understanding ion-molecular reactions is suggested to be essential to delineating the mechanisms of matrix-assisted laser desorption/ionization (MALDI) and related ionization methods. To examine the implications of matrix-analyte reactions in the reduction observed in MALDI, copper(II) chloride and riboflavin were analyzed by desorption/ionization on porous silicon (DIOS) mass spectrometry. This system does not require a matrix for soft laser desorption/ionization. The two susbstances were reduced by DIOS as well, and the reduction of riboflavin was accelerated using water as a solvent, as reported in MALDI. The results indicated that target-analyte electron transfer occurs in LDI, although the possibility of matrix-analyte electron transfer in MALDI cannot be excluded.},
 pages = {13--20},
 title = {Reduction of Cu(II) and Riboflavin in DIOS Mass Spectrometry},
 volume = {52},
 year = {2004}
}