{"created":"2023-05-15T12:20:48.136575+00:00","id":11496,"links":{},"metadata":{"_buckets":{"deposit":"ea0cb117-3e4d-4b67-82dd-31389adb6fdc"},"_deposit":{"created_by":1,"id":"11496","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11496"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011496","sets":["528:1588:1595:1597"]},"author_link":["26700","26697","26699","26695","26692","26694","26693","26698"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-10-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"1767","bibliographicPageStart":"1765","bibliographicVolumeNumber":"44","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Reaction of t-butylcalix[8] arene (BCA[8]) as an A8-type monomer with hexamethylene diisocyanate as a B2-type monomer was examined to afford only soluble polymers in high yields. Analysis by 1HNMR, IR, MALDI-TOF mass spectroscopy, and AFM indicated that the synthesized polymers consist of nanoscale-gel-shaped structures that contain fixed holes and cavities. We designated this class of polymers as botryosin, after the Greek word botrys, meaning a bunch of grapes. Examination of host-guest chemistry of the synthesized polymers revealed complexation with alkali metal ions.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"26697","nameIdentifierScheme":"WEKO"}],"names":[{"name":"工藤, 宏人"}]},{"nameIdentifiers":[{"nameIdentifier":"26698","nameIdentifierScheme":"WEKO"}],"names":[{"name":"静間, 基博"}]},{"nameIdentifiers":[{"nameIdentifier":"26699","nameIdentifierScheme":"WEKO"}],"names":[{"name":"久保, 光亮"}]},{"nameIdentifiers":[{"nameIdentifier":"26700","nameIdentifierScheme":"WEKO"}],"names":[{"name":"林, 智広"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/cl.150840","subitem_relation_type_select":"DOI"}}]},"item_9_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 2015 The Chemical Society of Japan"},{"subitem_rights":"本文は日本化学会の許諾を得て作成しています。"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03667022","subitem_source_identifier_type":"ISSN"}]},"item_9_text_35":{"attribute_name":"出版者（他言語）","attribute_value_mlt":[{"subitem_text_value":"日本化学会"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kudo, Hiroto"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Shizuma, Motohiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kubo, Kosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi, Tomohiro"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20151015-00.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20151015-00.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11496/files/KU-1100-20151015-00.pdf"},"version_id":"abb4bc9c-6ea5-41b6-86f0-1bd97b6ae643"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"関西大学","subitem_subject_scheme":"Other"},{"subitem_subject":"Kansai University","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Calixarene-polymers via Simple Polymerization of t-Butylcalix[8]arenes (A8-type Monomer) with Hexamethylene Diisocyanate (B2-type Monomer); Molecular Bunch of Grapes (Botryosin)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Calixarene-polymers via Simple Polymerization of t-Butylcalix[8]arenes (A8-type Monomer) with Hexamethylene Diisocyanate (B2-type Monomer); Molecular Bunch of Grapes (Botryosin)"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-06-12"},"publish_date":"2017-06-12","publish_status":"0","recid":"11496","relation_version_is_last":true,"title":["Calixarene-polymers via Simple Polymerization of t-Butylcalix[8]arenes (A8-type Monomer) with Hexamethylene Diisocyanate (B2-type Monomer); Molecular Bunch of Grapes (Botryosin)"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-05-15T15:38:40.741059+00:00"}