{"created":"2023-05-15T12:20:47.873971+00:00","id":11490,"links":{},"metadata":{"_buckets":{"deposit":"4e8ca842-0d2a-4a2f-8fea-f4728153437e"},"_deposit":{"created_by":1,"id":"11490","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11490"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011490","sets":["528:1588:1595:1597"]},"author_link":["26654","26645","26647","26652","26650","26651","26656","26653","26649","26648","26646","26655"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000-07-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1131","bibliographicPageStart":"1130","bibliographicVolumeNumber":"29","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"[Pt(hfac)2] (hfac:hexafluoroacetylacetonate) reacts with MeNH2 in CH2Cl2/MeOH to give an –NHMe adduct complex on one of the carbonyl carbons, (MeNH3)[Pt(hfac)(hfac–NHMe)] 1 which is a tetrahedral intermediate of a Schiff base complex,[Pt(CF3COCHC(NMe)CF3)2] 2. Complex 1 activates H2O,MeOH, MeNO2 or acetone in solution to form the corresponding\nconjugate base adducts. The C–C bond in–CH2NO2 adduct 6, easily cleaves and generates nitromethane in solution.","subitem_description_type":"Other"}]},"item_9_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"26651","nameIdentifierScheme":"WEKO"}],"names":[{"name":"桶矢, 成智"}]},{"nameIdentifiers":[{"nameIdentifier":"26652","nameIdentifierScheme":"WEKO"}],"names":[{"name":"橋本, 正人"}]},{"nameIdentifiers":[{"nameIdentifier":"26653","nameIdentifierScheme":"WEKO"}],"names":[{"name":"中村, 文子"}]},{"nameIdentifiers":[{"nameIdentifier":"26654","nameIdentifierScheme":"WEKO"}],"names":[{"name":"楠山, 芳章"}]},{"nameIdentifiers":[{"nameIdentifier":"26655","nameIdentifierScheme":"WEKO"}],"names":[{"name":"小林, 真子"}]},{"nameIdentifiers":[{"nameIdentifier":"26656","nameIdentifierScheme":"WEKO"}],"names":[{"name":"荒川, 隆一"}]}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan"}]},"item_9_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/cl.2000.1130","subitem_relation_type_select":"DOI"}}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00603318","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03667022","subitem_source_identifier_type":"ISSN"}]},"item_9_text_35":{"attribute_name":"出版者（他言語）","attribute_value_mlt":[{"subitem_text_value":"日本化学会"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Okeya, Seichi"}],"nameIdentifiers":[{"nameIdentifier":"26645","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hashimoto, Masato"}],"nameIdentifiers":[{"nameIdentifier":"26646","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakamura, Fumiko"}],"nameIdentifiers":[{"nameIdentifier":"26647","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kusuyama, Yoshiaki"}],"nameIdentifiers":[{"nameIdentifier":"26648","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kobayashi, Mako"}],"nameIdentifiers":[{"nameIdentifier":"26649","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arakawa, Ryuichi"}],"nameIdentifiers":[{"nameIdentifier":"26650","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20000707-10.pdf","filesize":[{"value":"92.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20000707-10.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11490/files/KU-1100-20000707-10.pdf"},"version_id":"d6fdf892-8e89-4259-8606-515428c215c0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Facile Formation and Dissociation Behaviour of C-C Bond Resulted from the Nucleophilic Attack of Carbanions on a Carbonyl Carbon in [Pt(hfac)2]","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Facile Formation and Dissociation Behaviour of C-C Bond Resulted from the Nucleophilic Attack of Carbanions on a Carbonyl Carbon in [Pt(hfac)2]"}]},"item_type_id":"9","owner":"1","path":["1597"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-01-26"},"publish_date":"2012-01-26","publish_status":"0","recid":"11490","relation_version_is_last":true,"title":["Facile Formation and Dissociation Behaviour of C-C Bond Resulted from the Nucleophilic Attack of Carbanions on a Carbonyl Carbon in [Pt(hfac)2]"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-05-15T18:28:59.343861+00:00"}