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The Facilitated Ion-Transfer of Lauryltrimethyl and Hexadecyltrimethylammonium Cations by Dibenzo Crown Ethers across the Water|1,2-Dichloroethane Interface
http://hdl.handle.net/10112/6188
http://hdl.handle.net/10112/61886367211a-3af2-41c1-b1f9-551d2f717cad
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-19991005-28.pdf (358.1 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2012-03-03 | |||||
| タイトル | ||||||
| タイトル | The Facilitated Ion-Transfer of Lauryltrimethyl and Hexadecyltrimethylammonium Cations by Dibenzo Crown Ethers across the Water|1,2-Dichloroethane Interface | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Bakshi, Mandeep Singh
× Bakshi, Mandeep Singh× Doe, Hidekazu× Sakurada, Norio× Arakawa, Ryuichi |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26595 | |||||
| 姓名 | 櫻田, 教夫 | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 26596 | |||||
| 姓名 | 荒川, 隆一 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The transfer of lauryltrimethylammonium(LTA+) and hexadecyltrimethyl-ammonium(HTA+) cations facilitated by dibenzo-15-crown-5(DB15C5), DB18C6 and DB21C7, from aqueous phase to 1,2-dichloroethane(DCE) phase were studied. In the presence of DB15C5, ambiguous wave was observed which became somewhat prominent in the presence of DB18C6 and then irreversible in the presence of DB21C7. Such waves have been attributed to the facilitated transfer of LTA+ and HTA+ cations across the interface in the form of surfactant ion-crown ether (CR) complexes. On the basis of electrospray ionization mass spectroscopy(ESI-MS) measurements, the stoichiometry of such a complex has been proposed to be 1:1. It has also been observed by interfacial tension (r) measurements that the facilitated transfer becomes irreversible once the immiscible interface is fully occupied by the adsorption of amphiphilic surfactant monomers. | |||||
| 書誌情報 |
Chemistry Letters 巻 28, 号 10, p. 1059-1060, 発行日 1999-10-05 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03667022 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00603318 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1246/cl.1999.1059 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | The Chemical Society of Japan | |||||
| 出版者（他言語） | ||||||
| 値 | 日本化学会 | |||||
