{"created":"2023-05-15T12:20:42.458139+00:00","id":11369,"links":{},"metadata":{"_buckets":{"deposit":"82086725-4264-4d9c-b307-cbffa59f62f1"},"_deposit":{"created_by":1,"id":"11369","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"11369"},"status":"published"},"_oai":{"id":"oai:kansai-u.repo.nii.ac.jp:00011369","sets":["528:1588:1592:1594"]},"author_link":["25829","25830","25831"],"control_number":"11369","item_9_alternative_title_20":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Behavior of Crystallization Stripping of Ag Carbonate and Ag-Ni Composite Carbonate and Their Physicochemical Properties : Studies on production of composite powders with crystallization stripping (2nd report)-","subitem_alternative_title_language":"en"}]},"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"688","bibliographicPageStart":"683","bibliographicVolumeNumber":"117","bibliographic_titles":[{"bibliographic_title":"資源と素材 : 資源・素材学会誌","bibliographic_titleLang":"ja"}]}]},"item_9_description_4":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"The behavior of the crystallization stripping of Ag carbonate and Ag-Ni composite carbonate was investigated using Versatic Acid 10 as an extractant and pressurized carbon dioxide as a crystallizing agent. The physicochemical properties such as crystal structure, thermal decomposition and distribution of Ag and Ni were also investigated on the obtained crystallized products.\nThe possibility of crystallization stripping of Ag and Ni from the organic phase has been confirmed by calculating the aqueous pH equilibrated with pressured carbon dioxide. The reaction of crystallization stripping of Ag and Ni depends on an extractant concentration, a pressure of carbon dioxide and a metal concentration in an organic phase. The obtained crystallized product of Ag is confirmed to be Ag2CO3 crystal, which is characterized by the needle like crystal or polyhedron crystal. Heating of the crystallized product of Ag in air and hydrogen causes a thermal decomposition to metal Ag powder. When the crystallization stripping is carried out from the organic phase containing Ag and Ni, the simultaneous crystallization takes place to form the composite carbonate of Ag and Ni. The composite carbonate consists of mixture of Ag2CO3 and NiCO3 · 2Ni(OH)2 · 4H2O.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_9_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"資源・素材学会","subitem_publisher_language":"ja"}]},"item_9_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"資源・素材学会（http://www.jstage.jst.go.jp/browse/shigentosozai/_vols/-char/ja）"}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN10062646","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09161740","subitem_source_identifier_type":"PISSN"}]},"item_9_version_type_17":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"奥田, 晃彦","creatorNameLang":"ja"},{"creatorName":"Okuda, Akihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"25829","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山本, 秀樹","creatorNameLang":"ja"},{"creatorName":"Yamamoto, Hideki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"25830","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30174808","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000030174808"}]},{"creatorNames":[{"creatorName":"芝田, 隼次","creatorNameLang":"ja"},{"creatorName":"Shibata, Junji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"25831","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70067742","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000070067742"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"KU-1100-20010000-10.pdf","filesize":[{"value":"908.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KU-1100-20010000-10.pdf","url":"https://kansai-u.repo.nii.ac.jp/record/11369/files/KU-1100-20010000-10.pdf"},"version_id":"ee919e80-ce53-49a7-8afe-6268fbb9a85d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"溶媒抽出（Solvent Extraction）","subitem_subject_scheme":"Other"},{"subitem_subject":"晶析剥離（Crystallization Stripping）","subitem_subject_scheme":"Other"},{"subitem_subject":"複合粉体（Composite Powders）","subitem_subject_scheme":"Other"},{"subitem_subject":"銀（Silver）","subitem_subject_scheme":"Other"},{"subitem_subject":"ニッケル（Nickel）","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ag粉体およびAg-Ni複合粉体の晶析剥離操作とその物性 : 晶析剥離法による複合粉体の製造に関する研究(第2報)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ag粉体およびAg-Ni複合粉体の晶析剥離操作とその物性 : 晶析剥離法による複合粉体の製造に関する研究(第2報)","subitem_title_language":"ja"}]},"item_type_id":"9","owner":"1","path":["1594"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2011-11-09"},"publish_date":"2011-11-09","publish_status":"0","recid":"11369","relation_version_is_last":true,"title":["Ag粉体およびAg-Ni複合粉体の晶析剥離操作とその物性 : 晶析剥離法による複合粉体の製造に関する研究(第2報)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-10-30T02:10:48.975649+00:00"}