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Further Discussion of Correlation between Brittleness and Network Structure of Triallyl Isocyanurate Resins
http://hdl.handle.net/10112/12449
http://hdl.handle.net/10112/124499b3b2e09-ff3f-4993-aeee-fd8fa8562012
名前 / ファイル | ライセンス | アクション |
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KU-1100-20070320-05.pdf (1.3 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2018-02-22 | |||||
タイトル | ||||||
タイトル | Further Discussion of Correlation between Brittleness and Network Structure of Triallyl Isocyanurate Resins | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
Matsumoto, Akira
× Matsumoto, Akira× Matsuda, Tomoya× Hirao, Chikaomi× Aota, Hiroyuki× Takayama, Yoshihiro× Toridome, Hiroyuki |
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著者別名 | ||||||
姓名 | 松本, 昭 | |||||
著者別名 | ||||||
姓名 | 松田, 知也 | |||||
著者別名 | ||||||
姓名 | 平尾, 親臣 | |||||
著者別名 | ||||||
姓名 | 青田, 浩幸 | |||||
著者別名 | ||||||
姓名 | 高山, 義弘 | |||||
著者別名 | ||||||
姓名 | 取溜, 博之 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Attempts to improve the toughness of triallyl isocyanurate (TAIC) resins were unsuccessful using the procedures developed for diallyl phthalate (DAP) resins as typical allyl resins by considering microinhomogenization of the DAP resin during polymerization beyond the gel-point conversion. This demonstrates the difference in network structure of TAIC and DAP resins. The structure of branched TAIC prepolymer was characterized as dendritic by SEC-MALLS-viscometry. Thus, an alternative explanation for the brittleness of TAIC resins is provided: the insufficient growth of the network structure of TAIC resin because of steric hindrance on the crosslinking reaction between sterically crowded growing polymer radical and pendant allyl groups belonging to the rigid primary polymer chain. | |||||
書誌情報 |
関西大学工学研究報告 = Technology reports of the Kansai University 巻 49, p. 39-53, 発行日 2007-03-20 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 04532198 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00046916 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 関西大学工学部 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 関西大学 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Kansai University |