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エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量
http://hdl.handle.net/10112/6009
http://hdl.handle.net/10112/60093ff79728-7756-4c7c-8790-a52cc4d3d9f4
名前 / ファイル | ライセンス | アクション |
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KU-1100-20040605-06.pdf (654.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-02-02 | |||||
タイトル | ||||||
タイトル | エレクトロスプレーイオン化質量分析法による超臨界反応生成物1,3-butadiene dicarbonateの定量 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
その他のタイトル | ||||||
その他のタイトル | Determination of 1,3-butadiene dicarbonate produced by supercritical reactions using electrospray lonization mass spectrometry | |||||
著者 |
植村, 誠治
× 植村, 誠治× 阿部, 一之× 荒川, 隆一 |
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著者別名 | ||||||
姓名 | Uemura, Seiji | |||||
著者別名 | ||||||
姓名 | Abe, Kazuyuki | |||||
著者別名 | ||||||
姓名 | Arakawa, Ryuichi | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 超臨界反応による1,3-butadiene diepoxide(BDE)から1,3-butadiene dicarbonate(BDC)へのCO_2導入反応を行った.エレクトロスプレーイオン化質量分析法(ESI-MS)により,反応生成物はアルカリ金属付加イオンとして検出できた.アルカリ金属塩の触媒効果を測定し,NaIが最も高い触媒活性を示した.その触媒の効果は,アルカリ金属原子とハロゲン原子のイオン半径差,又はハロゲンの電気陰性度の差に依存していること分かった.これらBDCなどのカーボネート化合物の分析にESI-MSが有効であることが分かった. \nThe introduction reaction of carbon dioxide from 1,3-butadiene diepoxide to 1,3-butadiene dicarbonate was studied using catalysts of various alkali halides in supercritical carbon dioxide(scCO_2). The reaction products were analyzed by electrospray ionization mass spectrometry(ESI-MS); also, the catalytic effect of alkali halides was examined. The results indicated that sodium iodide had the greatest catalytic effect among them. A tendency of the effect was considered based on the difference in the ion radius between alkaline metal and halogen, or the difference in the electronegativity of halogens. ESI-MS was a useful technique to analyze carbonate compounds formed by the scCO_2 reaction. |
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書誌情報 |
分析化学 巻 53, 号 6, p. 541-546, 発行日 2004-06-05 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 05251931 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 日本分析化学会 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | electrospray ionization mass spectrometry | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | supercritical carbon dioxide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 1,3-butadiene diepoxide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 1,3-butadience dicarbonate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | catalysis of alkali halides |