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Inclusion of Alkali Metal Ions by Permethylated Inulin Studied by Electrospray Ionization Mass and Multinuclear Nuclear Magnetic Resonance Spectrometric Approaches
http://hdl.handle.net/10112/6000
http://hdl.handle.net/10112/6000029a2f99-7852-48d8-bdd9-26d0ee366514
名前 / ファイル | ライセンス | アクション |
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KU-1100-20090000-01.pdf (747.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-02-02 | |||||
タイトル | ||||||
タイトル | Inclusion of Alkali Metal Ions by Permethylated Inulin Studied by Electrospray Ionization Mass and Multinuclear Nuclear Magnetic Resonance Spectrometric Approaches | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Takai, Yoshio
× Takai, Yoshio× Yamada, Hitoshi× Goshima, Gakuto× Iwahori, Yukimasa× Tanaka, Juichi× Arakawa, Ryuichi× Shizuma, Motohiro× Sawada, Masami |
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著者別名 | ||||||
姓名 | 高井, 嘉雄 | |||||
著者別名 | ||||||
姓名 | 山田, 等 | |||||
著者別名 | ||||||
姓名 | 五島, 学人 | |||||
著者別名 | ||||||
姓名 | 岩堀, 幸正 | |||||
著者別名 | ||||||
姓名 | 田中, 寿一 | |||||
著者別名 | ||||||
姓名 | 荒川, 隆一 | |||||
著者別名 | ||||||
姓名 | 靜間, 基博 | |||||
著者別名 | ||||||
姓名 | 澤田, 正寛 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Inclusions of alkali metal ions by permethylated inulin (MeInu) were examined by electrospray ionization (ESI) mass spectrometry and multinuclear nuclear magnetic resonance (NMR) spectroscopy. Complexes of MeInu with metal ions were observed as multicharged ions in ESI mass spectra. The number of fructofuranose units of MeInu binding to one metal ion was 12, 6, and 7 for Li+, K+, and Cs+, respectively, on the basis of ESI mass spectra. However, the number estimated on the basis of multinuclear NMR spectra was 2 and 3-4 for Li+ and K+, respectively. The binding ability of MeInu to Li+ is very weak, so metal ions dissociate from the complex in the ionization process. As a result, the ratio of fructofuranose units to Li+ ions might have been estimated in excess. In the case of K+ and Cs+, the number of fructofuranose units binding a metal ion is found to be in good agreement with that of the oxyethylene units of crown ethers in solution. | |||||
書誌情報 |
Journal of the Mass Spectrometry Society of Japan 巻 57, 号 1, p. 1-8, 発行日 2009 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13408097 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1254271X | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.5702/massspec.57.1 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | Mass Spectrometry Society of Japan | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Electrospray ionization mass spectrometry | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Multinuclear nuclear magnetic resonance spectroscopy | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Permethylated inulin | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Alkari metal ion | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Host-guest complexation | |||||
出版者(他言語) | ||||||
日本質量分析学会 |