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Measurement of Chiral Recognition Properties of Crown Ethers Using Matrix Assisted Laser Desorption Ionization Mass Spectrometry
http://hdl.handle.net/10112/5989
http://hdl.handle.net/10112/59890519d91f-96f9-4fc8-a4cd-0ba004fbb291
名前 / ファイル | ライセンス | アクション |
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KU-1100-20000000-10.pdf (319.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-02-02 | |||||
タイトル | ||||||
タイトル | Measurement of Chiral Recognition Properties of Crown Ethers Using Matrix Assisted Laser Desorption Ionization Mass Spectrometry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Sawada, Masami
× Sawada, Masami× Harada, Manabu× Takai, Yoshio× Nakano, Kazurou× Kuroda, Masao× Arakawa, Ryuichi |
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著者別名 | ||||||
姓名 | 澤田, 正寛 | |||||
著者別名 | ||||||
姓名 | 原田, 学 | |||||
著者別名 | ||||||
姓名 | 高井, 嘉雄 | |||||
著者別名 | ||||||
姓名 | 中野, 和郎 | |||||
著者別名 | ||||||
姓名 | 黒田, 正男 | |||||
著者別名 | ||||||
姓名 | 荒川, 隆一 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Hydrogen bonding host-guest complex ions between chiral crown ethers and chiral amino acid ester salts, detected by matrix assisted laser desorption ionization (MALDI) mass spectrometry (MS) with a DHBA or MSA matrix, were studied on the view point of chiral recognition properties of the chiral crown hosts. The chiral recognition property (IR/IS-dn value≅1.0) obtained by the present MALDI-MS is sharply different from the IR/IS-dn value obtained by FAB-MS or ESI-MS (≠1.0) in the same host-guest combinations. The direct comparison on the basis of the IR/IS-dn values suggests that MALDI-MS is not a suitable measurement tool for chiral host-guest interactions probably because of the particular way of sample preparation involving a crystallization process. | |||||
書誌情報 |
Journal of the Mass Spectrometry Society of Japan 巻 48, 号 2, p. 141-144, 発行日 2000 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13408097 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1254271X | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.5702/massspec.48.141 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | Mass Spectrometry Society of Japan | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | MALDI mass spectrometry | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chiral recognition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chiral crown ether | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Amino acid ester | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Deuterium labeling | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Cyclofructan | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Host-guest complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Non-covalent chiral | |||||
出版者(他言語) | ||||||
日本質量分析学会 |