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Oxidation of Ferrocene Derivatives in Desorption/Ionization on Porous Silicon
http://hdl.handle.net/10112/5900
http://hdl.handle.net/10112/5900575fe191-4373-4858-977f-70e2dbea7090
名前 / ファイル | ライセンス | アクション |
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KU-1100-20051210-11.pdf (56.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-01-20 | |||||
タイトル | ||||||
タイトル | Oxidation of Ferrocene Derivatives in Desorption/Ionization on Porous Silicon | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Okuno, Shoji
× Okuno, Shoji× Oka, Kunihiko× Arakawa, Ryuichi |
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著者別名 | ||||||
姓名 | 奥野, 昌二 | |||||
著者別名 | ||||||
姓名 | 岡, 邦彦 | |||||
著者別名 | ||||||
姓名 | 荒川, 隆一 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | In matrix-assisted laser desorption/ionization(MALDI),the true molecular structures of some analytes are not represented by the observed ions due to a redox reaction.In earlier reports,electron transfer from analyte to chemical matrix has been proposed for the oxidation of ferrocene derivatives in MALDI.To address such a redox phenomenon in laser desorption/ionization processes,two ferrocene derivatives,FcCH2CH2Fc and FcCH2NMe2[Fc:(C5H5)Fe(C5H4)],were analyzed by a matrix-free method,desorption/ionization on porous silicon(DIOS). The oxidized species,Fc+CH2NMe2 and FcCH2CH2Fc+,were detected in the DIOS mass spectra.The results suggested that electron transfer from the analytes to the sample target occurs during the ionization process. | |||||
書誌情報 |
Analytical Sciences 巻 21, p. 1449-1451, 発行日 2005-12-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09106340 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10500785 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.2116/analsci.21.1449 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry | |||||
出版者(他言語) | ||||||
日本分析化学会 |