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Electrospray Ionization Mass Spectrometry for Mechanism Analysis of Metal Ion Complexation and Photoionization of Malachite Green Derivatives Incorporating a Crown Ether Moiety
http://hdl.handle.net/10112/6065
http://hdl.handle.net/10112/60654ea7f173-443e-4076-9cb5-6c1553bdc5d7
名前 / ファイル | ライセンス | アクション |
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KU-1100-19990000-01.pdf (220.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-02-21 | |||||
タイトル | ||||||
タイトル | Electrospray Ionization Mass Spectrometry for Mechanism Analysis of Metal Ion Complexation and Photoionization of Malachite Green Derivatives Incorporating a Crown Ether Moiety | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kimura, Keiichi
× Kimura, Keiichi× Mizutani, Ryoko× Yokoyama, Masaaki× Arakawa, Ryuichi |
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著者別名 | ||||||
姓名 | 木村, 恵一 | |||||
著者別名 | ||||||
姓名 | 水谷, 良子 | |||||
著者別名 | ||||||
姓名 | 横山, 正明 | |||||
著者別名 | ||||||
姓名 | 荒川, 隆一 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Electrospray-ionization mass spectrometry using a photoirradiation interface has been successfully applied to the investigation of metal-ion complexation and photoionization of crowned Malachite Green leuconitrile derivatives in solution. The mass spectrometry clearly showed that the Malachite Green derivatives in their electrically neutral forms can complex metal ions with their crown ether moiety. Ionization of the Malachite Green derivatives to their corresponding cationic forms, accompanied by metal-ion repelling from their crown ether moiety, was detected upon UV-light irradiation. A remarkably different photoionization behavior in various solvents, which is difficult to detect by other analytical techniques, was also found by the mass spectrometry. | |||||
書誌情報 |
Analytical Chemistry 巻 71, p. 2922-2928, 発行日 1999 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00032700 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00524878 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/ac981230n | |||||
権利 | ||||||
権利情報 | Copyright(C)1999 American Chemical Society | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | American Chemical Society |