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Effect of Short-Chain Alkylamine on Micelle Structure in MCM-41 Synthesis Process
http://hdl.handle.net/10112/5523
http://hdl.handle.net/10112/55232a26b68c-c1fc-4a09-91ba-e40a34cb64b4
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KU-1100-20070100-01.pdf (469.1 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2011-11-11 | |||||
| タイトル | ||||||
| タイトル | Effect of Short-Chain Alkylamine on Micelle Structure in MCM-41 Synthesis Process | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Lee, Hyoung-Ho
× Lee, Hyoung-Ho× Shibata, Junji× Ahn, Ji-Whan× Kim, Hwan |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 25494 | |||||
| 姓名 | 芝田, 隼次 | |||||
| 概要 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | It was found that MCM-41 mesostructure can be strengthened by using ethylamine as a mineralizer in our previous study. The addition of ethylamine causes structural changes at the same time. In this report, important factors deciding micelle formation and possible changes in conformation of micelle when small amphiphilic materials co-exist are discussed. Incorporation of short-chain alkylamine in micelle is predicted by the energetical consideration if alkylamine is in neutral state and has an adequately hydrophobic chain part. Ethylamine which is supposed to be neutral in the pH range above pKa is found to incorporate in micelle when alcohol coexists together and increases hydrophobicity of ethylamine by forming complex with it. The same phenomenon takes place even without the addition of alcohol when alkylamine having a longer alkylchain such as propylamine and butylamine is used because of increased hydrophobicity. | |||||
| 書誌情報 |
環境資源工学 巻 54, 号 3, p. 116-121, 発行日 2007-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 13486012 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11907992 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | 環境資源工学会 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | mesoporous | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | MCM-41 | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | alkylamine | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | micelle | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cosurfactant | |||||
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Cite as
Lee, Hyoung-Ho, Shibata, Junji, Ahn, Ji-Whan, Kim, Hwan, 2007, Effect of Short-Chain Alkylamine on Micelle Structure in MCM-41 Synthesis Process: 環境資源工学会, 116–121 p.
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